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Perhaps Thurston’s best known achievement is the proof of the hyperbolisation theorem for Haken manifolds, which showed that 3-manifolds which obeyed a certain number of topological conditions, could always be given a hyperbolic geometry (i.e. a Riemannian metric that made the manifold isometric to a quotient of the hyperbolic 3-space ). This difficult theorem connecting the topological and geometric structure of 3-manifolds led Thurston to give his influential geometrisation conjecture, which (in principle, at least) completely classifies the topology of an arbitrary compact 3-manifold as a combination of eight model geometries (now known as Thurston model geometries). This conjecture has many consequences, including Thurston’s hyperbolisation theorem and (most famously) the Poincaré conjecture. Indeed, by placing that conjecture in the context of a conceptually appealing general framework, of which many other cases could already be verified, Thurston provided one of the strongest pieces of evidence towards the truth of the Poincaré conjecture, until the work of Grisha Perelman in 2002-2003 proved both the Poincaré conjecture and the geometrisation conjecture by developing Hamilton’s Ricci flow methods. (There are now several variants of Perelman’s proof of both conjectures; in the proof of geometrisation by Bessieres, Besson, Boileau, Maillot, and Porti, Thurston’s hyperbolisation theorem is a crucial ingredient, allowing one to bypass the need for the theory of Alexandrov spaces in a key step in Perelman’s argument.)
One of my favourite results of Thurston’s is his elegant method for everting the sphere (smoothly turning a sphere in inside out without any folds or singularities). The fact that sphere eversion can be achieved at all is highly unintuitive, and is often referred to as Smale’s paradox, as Stephen Smale was the first to give a proof that such an eversion exists. However, prior to Thurston’s method, the known constructions for sphere eversion were quite complicated. Thurston’s method, relying on corrugating and then twisting the sphere, is sufficiently conceptual and geometric that it can in fact be explained quite effectively in non-technical terms, as was done in the following excellent video entitled “Outside In“, and produced by the Geometry Center:
In addition to his direct mathematical research contributions, Thurston was also an amazing mathematical expositor, having the rare knack of being able to describe the process of mathematical thinking in addition to the results of that process and the intuition underlying it. His wonderful essay “On proof and progress in mathematics“, which I highly recommend, is the quintessential instance of this; more recent examples include his many insightful questions and answers on MathOverflow.
I unfortunately never had the opportunity to meet Thurston in person (although we did correspond a few times online), but I know many mathematicians who have been profoundly influenced by him and his work. His death is a great loss for mathematics.